Synthesis and Characterization of Lithium Borate Glasses Containing Bismuth

نویسندگان

  • M. Kaur
  • M. S. Saini
  • G. S. Mudahar
چکیده

A lithium bismuth borate glass system is prepared by the conventional melt quenching technique. The Powder X-Ray diffraction analysis of the prepared samples confirms the amorphous nature of the samples. The density and molar volume studies report the change of structure with the increase of bismuth content. The FTIR analysis of the samples revealed that the network structure of the prepared samples is mainly based on the BO3 and BO4 units. From the UV-Vis spectra it has been observed that the bandgap decreases with an increase in Bi2O3 content. The refractive index also decreases with an increase in wavelength. Optical basicity increases with an increase in Bi2O3 content.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Structural Investigation, Physical and Optical Properties of Mixed Alkali Bismuth Borate Glasses

Lead free, eco-friendly bismuth borate glasses doped with alkali oxides of composition xLi2O+(30-x)Na2O+55B2O3+15Bi2O3 (x = 5,10,15,20,25) were prepared by melt quenching technique. Amorphous nature of glasses was confirmed by X-ray diffraction. Density measurements were carried out at room temperature by standard principle of Archimedes with Xylene as an immersion liquid. The non-linear ...

متن کامل

Doped Zinc Lithium Bismuth Borate Glasses

Zinc lithium bismuth borate glasses containing Er in (25x): Bi2O3:20Li2O:20ZnO: 35B2O3:xEr2O3 (where x=1, 1.5,2 mol %) have been prepared by melt-quenching method. The amorphous nature of the glasses was confirmed by x-ray diffraction studies. Optical absorption and fluorescence spectra were recorded at room temperature for all glass samples. Judd-Ofelt intensity parameters Ωλ (λ=2, 4, 6) are e...

متن کامل

The Fluorescence of Pr3+ in Zinc Lithium Bismuth Borate Glasses with Large Stimulated Emission Cross Section

Glass sample of Zinc Lithium Bismuth Borate (25−x) Bi2O3:20Li2O:20ZnO:35B2O3:xPr6O11, (where x = 1, 1.5 and 2 mol%) has been prepared by melt-quenching technique. The amorphous nature of the prepared glass samples was confirmed by X-ray diffraction. The absorption spectra of three Pr3+ doped zinc lithium bismuth borate glasses have been recorded at room temperature. The observed optical spectra...

متن کامل

Optical Basicity and Polarizability of Nd3+-Doped Bismuth Borate Glasses

This paper reports on different physical and optical properties of Nd3+-doped bismuth borate glasses. The glasses containing Nd3+ in (25 − x)Bi2O3:20Li2O:20ZnO:35B2O3:xNd2O3 (where x = 1, 1.5, 2 mol%) have been prepared by melt-quenching method. The amorphous nature of the glasses was confirmed by X-ray diffraction studies. The physical parameters like dielectric constant, refractive index, ion...

متن کامل

Structural Characterization of fly ash doped lithium borate Glasses

Lithium borate glasses with fixed alkali content of 10 Mole % and different modifiers have been prepared. To compare the role of fly ash as a glass modifier the content of glass modifier PbO, Al2O3 have been kept same to 5 mole %. To investigate the structure FTIR and UV-VIS spectra of prepared samples have been taken. From optical data optical band gap and cutoff wavelength have been calculate...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2014